Vaporization methods for different liquids
In semiconductor devices, which require greater integration and detail, a variety of liquid sources are used to produce the thin films. HoribaSTEC offer a number of vaporization systems to accuratley control the precursor.
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Direct liquid injection systems
Liquid (no carrier gas) vaporization system

|
Process
|
Film |
Precursor |
Formula |
|
|
|
|
| ILD |
SiO2 |
TEOS |
Si(OC2H5)4 |
| ILD Low-K |
SiCO |
OMCTS |
[SiO(CH3)2-]4 |
| TMCST |
[SiOH(CH3)-]4 |
| HMDSO |
(CH3)3SiOSiO(CH3)3 |
| BPSG |
BPSG |
TEOS |
Si(OC2H5)4 |
| TEB |
B(OC2H5)3 |
| TMB |
B(OCH3)3 |
| TMP |
P(OCH3)3 |
| TMOP |
PO(OCH3)3 |
| TEOP |
PO(OC2H5)3 |
| Etch Stopper |
Si3N4 |
HCD |
Si2Cl6 |
| Gate Dielectric |
SiO2 |
TEOS |
Si(OC2H5)4 |
| High-K Gate |
Ta2O5 |
PETa |
Ta(OC2H5)5 |
| HfO2 |
TEMAH |
Hf[N(CH3)(C2H5)]4 |
| TDMAH |
Hf[N(CH3)2]4 |
| TDEAH |
Hf[N(C2H5)2]4 |
| ZrO2 |
TDMAZr |
Zr[N(CH3)2]4 |
| TDEAZr |
Zr[N(C2H5)2]4 |
| D-RAM Capacitor |
SiO2 / Si3N4 |
TEOS |
Si(OC2H5)4 |
| High-K Capacitor |
Ta2O5 |
PETa |
Ta(OC2H5)5 |
| BST |
Ba(DPM)2 |
Ba(O2C11H19)2 |
| Sr(DPM)2 |
Sr(O2C11H19)2 |
|
Ti(i-OC3H7)4 |
| FeRAM Capacitor |
PZT |
Pb(DPM)2 |
Pb(O2C11H19)2 |
| Zr(DPM)4 |
Zr(OC11H19)4 |
|
Zr(t-OC4H9)4 |
|
Ti(i-OC3H7)4 |
| SBT |
Bi(DPM)3 |
Bi(DPM)3 |
| Sr(DPM)2 |
Sr(O2C11H19)2 |
| PETa |
Ta(OC2H5)5 |
| Electrode |
Ru/RuO |
Ru-EtCp |
Ru(C5H4C2H5)2 |
| Barrier Metal |
TiN |
TDMAT |
Ti[N(CH3)2]4 |
| TDEAT |
Ti[N(C2H5)2]4 |
| TaN |
TBTDET |
Ta(N-t-C5H11)[N(CH3)2]3 |
|